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Chemical · Seminar 07 · Drop-in jet fuel without fossil carbon

Sustainable Aviation Fuel (SAF) Synthesis

Sustainable aviation fuel is made from waste oils, biomass or captured CO₂ and green hydrogen, cutting lifecycle emissions while remaining chemically compatible with today's jet engines.

SAFFischer-TropschHEFAe-fuelaviationdecarbonisation

Aviation is hard to electrify because batteries are too heavy for long flights. Sustainable aviation fuel (SAF) is the leading near-term answer: a drop-in kerosene that works in existing engines and pipelines but is made from sustainable carbon, cutting lifecycle CO₂ by up to ~80% versus fossil jet fuel.

Working principle

Several certified pathways exist. HEFA hydrotreats waste fats and oils into paraffinic kerosene — the most mature route. Gas/biomass-to-liquid routes gasify feedstock to syngas (CO + H₂), then use Fischer–Tropsch synthesis over a catalyst to build hydrocarbon chains, which are refined to jet range. The frontier route, Power-to-Liquid (e-fuel), combines captured CO₂ with green hydrogen to synthesise fully synthetic kerosene.

Feedstock (waste oil / CO₂+H₂)1Convert to intermediates2Fischer–Tropsch / hydrotreat3Refine to jet range4Blend → drop-in SAF5Generalised SAF production and upgrading
Figure 1. Sustainable carbon sources are converted and refined into paraffinic kerosene that meets jet-fuel specifications and blends with conventional fuel.
Table 1. Major SAF production pathways
PathwayFeedstockMaturity
HEFAWaste oils & fatsCommercial
Fischer–Tropsch (BtL/GtL)Biomass / waste → syngasDemonstration–early commercial
Alcohol-to-JetEthanol / isobutanolEmerging
Power-to-Liquid (e-SAF)CO₂ + green H₂Pilot / scaling
Key insightSAF's value is being drop-in: no new aircraft or infrastructure needed. The constraints are feedstock availability and cost — especially the energy needed for e-fuels.

Applications

  • Blending into commercial jet fuel to meet aviation climate mandates
  • E-fuels for routes where biomass feedstock is scarce
  • Co-production of renewable diesel and chemicals

References & further reading

  1. ICAO, “Sustainable Aviation Fuels Guidance and CORSIA framework,” 2023.
  2. Schmidt et al., “Power-to-Liquids as Renewable Fuel Option for Aviation,” Chemie Ingenieur Technik, 2018.
  3. Wang et al., “Review of biojet fuel conversion technologies,” Renew. Sustain. Energy Rev., 2019.